Biology Chemistry Electron in Proton Transfer

Life on earth depends on the photosynthetic use of solar energy by plants, and efforts to develop alternative sources of energy include a major thrust toward the use of photosynthesis to yield fuels. The study of photosynthesis is an especially convincing way of bringing together the disciplines of physics, chemistry, and biology and can be a valuable element in the teaching of biophysics and biochemistry. This book provides the only detailed modern treatment of the subject in a concise form. Part I outlines the historical development of the subject, emphasizing the chemical nature of photosynthesis and the roles of chlorophylls and other pigments. Part II reviews our present knowledge of the structure and components of photosynthetic tissues in relation to their function. Part III deals with the photo-chemistry of photosynthesis and with the patterns of chemical events, principally electron and proton transfer, that follow the photo-chemistry. Part IV treats the relationships of electron and proton transport to ATP formation, and the metabolic patterns of carbon assimilation. An epilogue exposes major areas of confusion and ignorance and indicates potentially fruitful directions of research, including the development of photosynthetic systems for solar energy conversion. Throughout the book, there are frequent digressions into those aspects of optics and molecular physics relevant to the subject matter. Suitable for upper undergraduate and graduate course use, this book is also sufficiently detailed to give professional scientists a perspective of the subject at the level of contemporary research.

One-electron reduction - A one-electron reduction in organic chemistry involves the transfer of an electron from a metal to an organic substrate. It serves to differentiate between true organic reductions and other reductions such as hydride transfer reactions that actually involve two-electron species.

Electron transport chain - The electron transport chain (also called the electron transfer chain, ETC, e-train, or simply electron transport), is any series of protein complexes and lipid-soluble messengers that convert the reductive potential of energized electrons into a cross-membrane proton gradient. Electron transport chains are used in photophosphorylation and respiration.

Rudolph A. Marcus - Rudolph "Rudy" Arthur Marcus (born July 21, 1923) received the 1992 Nobel Prize in Chemistry for his theory of Electron transfer. The Marcus Theory provides a thermodynamic and kinetic framework for describing one electron outer-sphere electron transfer.

Inner sphere electron transfer - Inner sphere electron transfer is a specific type of electron transfer reaction (ET) in which a common ligand bridges the two metal redox centers during the electron transfer event. The main proponent of the inner sphere ET was Henry Taube (Stanford), who won the Nobel Prize in 1983 for his concerning this topic.

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